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| PE分子结构对改性沥青黏弹性能及微观结构的影响 |
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梁明1,蒋福山2,范维玉1,辛雪1,李军1,王琼1,罗辉1,南国枝1
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(1.中国石油大学重质油国家重点实验室,山东青岛 266580;2.中石油燃料油有限责任公司研究院,北京 100089)
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| 摘要: |
| 利用动态剪切流变仪、荧光显微镜等手段研究不同结构PE改性沥青的黏弹性能、微观结构、黏温特性等,从聚合物分子结构的角度阐述改性沥青性能的差别及原因。结果表明:改性沥青在相同温度下的储存模量G′和损失模量G″由大到小顺序为HDPE、LDPE、VPE,储存模量G′随温度降低幅度大小顺序为VPE、LDPE、HDPE;相同温度下沥青质含量较低的ZH沥青的储存模量G′小于QHD沥青的;PE以不规则颗粒分散在沥青相中,LDPE分散最均匀,粒子为球状且直径约为20 μm;HDPE的粒子形状不规则且粒径多数大于100 μm;PE改性沥青微观结构及黏弹力学性能的差别是由于PE分子间距、分子柔顺性及结晶度的差异造成的;HDPE对沥青的黏弹力学性能和高温性能的提高效果最明显,HDPE合适的掺加量为4％～5％。 |
| 关键词: PE改性沥青 黏弹性 微观结构 |
| DOI：10.3969/j.issn.1673-5005.2016.06.022 |
| 分类号::U 414 |
| 文献标识码:A |
| 基金项目:中央高校基本科研业务费专项(24720156046A);中国石油大学研究生创新工程项目(15CX06046A) |
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| Effects of polyethylene molecular structure on the viscoelastic properties and microstructure of PE modified asphalt |
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LIANG Ming1, JIANG Fushan2, FAN Weiyu1, XIN Xue1, LI Jun1, WANG Qiong1, LUO Hui1, NAN Guozhi1
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(1.State Key Laboratory of Heavy Oil Processing in China University of Petroleum, Qingdao 266580, China;2.Research Institute of PetroChina Fuel Oil Company Limited, Beijing 100089, China)
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| Abstract: |
| Effects of polyethylene molecular structure on the viscoelastic properties, microstructure, and viscosity-temperature properties of PE modified asphalt were studied by means of dynamic shear rheometer and fluorescence microscopy, etc. The discrepancy of various polyethylene modified asphalt on performance was illustrated from the perspective of the polymer molecular structure. The results indicate that storage modulus G′ and loss modulus G″ of various binders decrease by the order of HDPE, LDPE and VPE, while the descending degree of storage modulus G′ with temperature diminished by VPE, LDPE and HDPE. The storage modulus of ZH asphalt is less than that of QHD asphalt because the asphaltene content in ZH asphalt is smaller. The particles of PE dispersed in asphalt are irregular and the particles of LDPE are the most uniform with diameters of 20 μm. Dispersed particles of HDPE are irregular and most of them are greater than 100 μm. The difference of the viscoelastic properties and microscopy among various polyethylene modified asphalts are caused by intermolecular distance, molecular flexibility and crystallinity. Meanwhile, HDPE is the most effective additive for asphalt modification, which enhances the mechanics and high-temperature performance. And the appropriate adding percentage of HDPE to asphalt is from 4％ to 5％. |
| Key words: polyethylene modified asphalt viscoelastic properties microstructure |
