摘要: |
烷基铵盐改性黏土的研究近年来引起了国内外学者的广泛关注,双价季铵盐的开发和利用为改性黏土的制备 与性能研究开辟了新途径。综述了双价短链季铵盐及其复配体系改性黏土的吸附、膨胀性、稳定性、润湿性和催化 性能,指出其基础研究的发展方向为有机改性黏土微观结构变化、水化膨胀过程中结合水类型的确定和界限的划 分、结合水与有机改性黏土的水合机制等。 |
关键词: 双价短链季铵盐 改性黏土 吸附 性能 进展 |
DOI: |
分类号: |
基金项目: |
|
Research advances in clay modified by bis-quaternary ammonium salt with short-chain |
GAO Mang-lai, SUN Li-min, LI Xiao-yan
|
(State Key Laboratory of Heavy Oil Processing in China University of Petroleum,Beijing 102249, China)
|
Abstract: |
The researches of clay modified by alkyl ammonium salts attracted the scholars' wide attention in China and abroad in recent years. The development and application of bis-quaternary ammonium salts opened a new way for the preparation and the property research of modified clays. The adsorption, swellability, stability, wettability and catalytic activity of the clays modified by bis-quaternary ammonium salt with short-chain and their composites were reviewed. The following are the developing trend of the basic research in this field : the microstructural changes of the organoclays,the type of combined water and boundary of hydration in clay swelling process as well as the hydration mechanism of combined water interacting with organo- |
Key words: bis-quatemary ammonium salt with short-chain modified clay adsorption property advances |