纳米SiO2降黏剂的制备及其提高普通稠油采收率性能研究
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    摘要:

    针对新疆油田某普通稠油水驱效果差,常规化学驱提高采收率低的问题,本文研究了一种新型的纳米降黏剂用于普通稠油化学驱。通过乙烯基三甲氧基硅烷对纳米SiO2表面改性,制备含碳碳双键的中间体SiO2@D,并进一步与α-烯基磺酸钠(AOS)接枝共聚,制备了两亲性纳米降黏剂SiO2@AOS。通过FT-IR、TG及SEM表征证实其成功合成。SiO2@AOS呈球形,平均直径15.6 nm。SiO2@AOS纳米流体(3 g/L)可将油水界面张力由31 mN/m降至4.4 mN/m(降幅85.8%),接触角由107.2°(疏水)调控至54.3°(亲水),显著改变储层润湿性;SiO2@AOS纳米流体(3 g/L)对该普通稠油(62℃, 1300 mPa.s)的降黏率达89.5%,乳状液的析水率达90.2%。SiO2@AOS纳米流体(3 g/L)驱及后续水驱可在一次水驱基础上再提高采收率22.5%。本研究为普通稠油化学驱提供了兼具高效降黏与驱油协同的新型纳米材料,具有重要应用潜力。

    Abstract:

    To address the challenges of low water flooding efficiency and limited enhanced oil recovery (EOR) from conventional chemical flooding in conventional heavy oil reservoirs of Xinjiang Oilfield, this study investigated a novel nano viscosity reducer for chemical flooding applications. Nano-SiO? was modified with vinyltrimethoxysilane to prepare an intermediate SiO2@D containing carbon-carbon double bonds, followed by graft copolymerization with α-olefin sulfonate (AOS) to synthesize an amphiphilic nano-viscosity reducer (SiO2@AOS). Successful synthesis was confirmed by FT-IR, TG, and SEM characterizations. The results revealed that SiO2@AOS forms spherical nanoparticles with an average diameter of 15.6 nm. The SiO2@AOS nanofluid (3 g/L) reduced oil water interfacial tension from 31 mN/m to 4.4 mN/m (an 85.8% reduction) and adjusted the contact angle from 107.2° to 54.3°, significantly altering reservoir wettability. The SiO2@AOS nanofluid (3g/L) achieved an 89.5% viscosity reduction rate for the conventional heavy oil (62 °C, 1300 mPa.s) and demonstrated 90.2% water separation efficiency in the emulsion system. The SiO2@AOS nanofluid (3 g/L) flooding and subsequent water flooding can further enhance oil recovery rate by 22.5% based on primary water flooding. This work provided a novel nanomaterial with dual functionalities of high efficiency viscosity reduction and synergistic oil displacement for conventional heavy oil production, showing significant application potential.

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  • 收稿日期:2025-05-19
  • 最后修改日期:2025-06-24
  • 录用日期:2025-07-02
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