分散剂对CSH纳米晶种粒径及早强作用的影响规律及机制
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    摘要:

    水化硅酸钙(CSH)纳米晶种凭借纳米尺寸效应与晶核诱导作用,可显著加速水泥水化产物的生长,具有优异早强性能。晶种制备过程需要加入分散剂来防止纳米晶种团聚,分散剂种类会显著影响CSH的粒径、形貌特征、分散稳定性和早强效果,但具体影响规律仍不清楚。本工作系统探究了聚羧酸、磺化醛酮、木质素磺酸钠三类不同结构分散剂对CSH结构-性能的调控,揭示了分散剂与早强性能的影响关系。结果表明:聚羧酸的密集侧链结构通过羧基配位与空间位阻作用,在0.3-0.7wt%浓度范围内使CSH粒径显著降低,并诱导CSH形成箔片状形貌;磺化醛酮线性分子通过层间插入诱导形成长箔片状CSH,而木质素磺酸钠的复杂网状结构通过磺酸基配位及引气效应生成球状CSH。同时,CSH早强性能与形貌-接枝效果密切相关,CSH-聚羧酸因高比表面积与聚羧酸的协同作用使12h抗压强度提升108%,显著优于CSH-磺化醛酮(66%)和CSH-木质素磺酸钠(79%)。

    Abstract:

    Calcium silicate hydrate (CSH) nanocrystalline seeds can significantly accelerate the growth of cement hydration products by virtue of nano size effect and crystal nucleus induction, and have excellent early strength properties. Dispersants need to be added in the seed preparation process to prevent the agglomeration of nanocrystalline seeds. The type of dispersants will significantly affect the particle size, morphology characteristics, dispersion stability and early strength of CSH, but the specific influence law is still unclear. In this work, we systematically explored the effect of polycarboxylate, sulfonated aldehyde ketone and sodium lignosulfonate dispersants with different structures on the structure property of CSH, and revealed the relationship between dispersants and early strength properties. The results show that the dense side chain structure of polycarboxylic acid can significantly reduce the particle size of CSH in the concentration range of 0.3-0.7wt% and induce CSH to form a foil like morphology through carboxyl coordination and steric hindrance; Sulfonated aldehydes and ketones form long foil CSH through intercalation, while the complex network structure of sodium lignosulfonate generates spherical CSH through sulfonic acid coordination and air entrainment effect. At the same time, the early strength of CSH is closely related to the morphology grafting effect. Due to the synergistic effect of high specific surface area and polycarboxylate, the 12h compressive strength of CSH polycarboxylate is increased by 108%, which is significantly better than that of CSH sulfonated aldehyde ketone (66%) and CSH lignosulfonate sodium (79%).

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  • 收稿日期:2025-04-29
  • 最后修改日期:2025-05-29
  • 录用日期:2025-07-02
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