界面聚合构筑MOF/MOC复合膜用于染料分离
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    摘要:

    有机染料作为常见的有毒污染物,对人类和水生生物构成严重威胁。将具有固有微孔的晶态多孔材料(如金属有机框架MOF和金属有机笼MOC)与聚合物结合,可制备出具有高渗透率和高选择性的膜材料,用于有效去除染料。本论文通过将MOF作为水相单体,与有机相单体均苯三甲酰氯(TMC)进行界面聚合,并在此基础上利用MOC二次界面聚合进行MOF与TMC间空隙的密封。利用这种方法可制备出一种连续致密的MOF/MOC复合膜。该复合膜具有独特的孔结构,包括界面聚合过程中形成的网状孔和晶态多孔材料的固有微孔,这赋予了其高透水性和良好的筛分性。实验结果表明,该复合膜具有18 Lm-2h-1bar-1的水渗透率及99.9%的染料去除率,在去除水溶液中有机染料方面展示出显著优势。

    Abstract:

    Organic dyes are common toxic pollutants that pose a serious threat to humans and aquatic life. Metal-organic framework (MOF) and Metal-organic cage (MOC), combined with polymers can leverage their inherent pore structures to create membranes with high permeability and selectivity for effective dye removal. This paper reports the use of MOF as the aqueous phase monomer for interfacial polymerization with the organic phase monomer (trimesoyl chloride, TMC). Subsequently, a secondary interfacial polymerization using MOC was performed to fix the voids between MOF and TMC. The resulting membrane exhibits a dense structure and a high loading of porous material. The composite membrane possesses a unique pore structure, including the network pores formed during interfacial polymerization and the intrinsic micropores of the crystalline porous material, which provides the membrane with high water permeability and excellent sieving performance. Experimental results show that the composite membrane has a water permeance of 18 Lm-2h-1bar-1 and a dye removal rate of 99.9%, demonstrating that composite membranes constructed using crystalline porous materials as the aqueous phase monomer are highly effective in removing soluble pollutants from aqueous solutions.

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  • 收稿日期:2025-02-19
  • 最后修改日期:2025-04-01
  • 录用日期:2025-05-19
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