耐温聚合物减阻剂的制备及耐温滑溜水的减阻机制研究
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    摘要:

    针对常规滑溜水压裂液耐温性不足等问题,通过自由基聚合法合成了一种适用于深层页岩储层油气开发的耐温聚合物减阻剂YTRP,利用红外光谱等手段对其结构进行了表征,并以YTRP为压裂液主剂构筑了耐温滑溜水压裂液体系,对体系的综合性能进行了评价,最后借助流变实验与微观表征揭示YTRP减阻剂减阻机理。结果表明,相较于同分子量的部分水解聚丙烯酰胺HPAM,耐温滑溜水体系具有更优异的耐温耐剪切性、配伍性,在高温条件下减阻性能优异(120℃时减阻率为72.6%),储层伤害性低(岩心伤害率为11.72%),防膨性能好(CST比值为1.01)。相较于HPAM,YTRP分子柔顺性更好,经历高温环境后保留的结构强度更高;通过聚合物减阻剂的黏性与弹性协同增效,聚合物链形成的网络结构在与湍流相互作用的过程中,能够有效实现能量的储存与释放,降低能量损耗,达到高温下更好的减阻效果。

    Abstract:

    To address the problem of insufficient temperature resistance of conventional slickwater fracturing fluid, a type of temperature resistant polymer drag reducer (YTRP) was synthesized by free radical polymerization method. Infrared spectroscopy and other methods were used to analyze its structure, and a temperature-resistant slickwater fracturing fluid system was built with YTRP as the primary agent. Then the comprehensive performance of the system was evaluated. Ultimately, the drag reduction mechanism of YTRP was discovered through rheological experiments and microscopic characterization. The results showed that the slickwater system had superior temperature and shear resistance, compatibility when compared with HPAM of the same molecular weight. In addition, it exhibits excellent drag reduction performance at high temperature (the drag reduction rate was 72.6% at 120℃), low reservoir damage (the core damage rate was only 11.72%) and good anti-swelling performance (the CST ratio was 1.01). Compared with HPAM, YTRP has better molecular flexibility and retains higher structural strength after high temperature environment. Through the synergistic effect of viscosity and elasticity of the polymer drag reducer, the network structure created by the polymer chain can efficiently realize energy storage and release during the interaction with turbulence, which limit energy loss, and achieve better drag reduction effect at high temperature.

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  • 收稿日期:2023-11-27
  • 最后修改日期:2024-02-28
  • 录用日期:2024-03-29
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